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Well if your cat is bad then it would explain why you smell gas or a "nasty" smell, after all the cat is what filters all the shit, so to speak.
I would get that fixed first and foremost and get rid of the CEL.
As for the overheating: You are not turbo are you? If you aren NOT turbo then the only was you can run lean is with bad/dirty injectors because there is a stock fuel control which cannot be changed.
First I would check if the waterpump is dead along with the other coolant/radiator stuff. In worst case scenario it could be the headgasket since I read that can also cause it. But forget that for now and work on the smallest possibilities first.
Are you loosing coolant? I did when my water pump broke. Check the coolant as well.
My suspicion is that the smell and overheating don't really have anything to do with each other.
gas smell ---> cat problem overheating -----> radiator/waterpump/coolant problem MODS:
HRC 16g turbo kit, Spearco custom FMIC, Custom IC piping, VT rebuilt engine: Custom 8.8:1 compression CP pistons, Eagle connecting rods, Melling oil pump, Clevite bearings, 370cc injectors, Vortech S-FMU, Apexi N-1 catback exhaust, AFX UDP, Autometer boost gauge, fuel pressure gauge, EGT gauge, Corbin's digital A/F gauge, Tokico Blue shocks, Tein springs (1.5" drop), 18" Konig Verdicts rims, VIS stock-style Carbon fiber hood
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