I spray painted my rims gunmetal. I just used a base black engine paint (500 degree) and then put gunmetal duplicolor brand paint over it. Hades told me about it. It's sold as a touchup paint for Ford and other trucks I think, so it's just normal paint. Do very thin coats. I can tell it's painted up close, but others that don't know can't tell at all. I guess you would have to examine it more closely in order to tell it's painted. Some of my friends actually thought I got new rims hehe.

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2004 WRX - WR Blue Pearl
1997 Eclipse GS - Royal Sapphire Pearl